Product ID:BREAK-FREE CLP,AEROSOL
MSDS Date:03/02/1993
FSC:6850
NIIN:00-105-3084
MSDS Number: BJPJM

BREAK-FREE DIV OF SAN/BAR CORP

1035 S LINWOOD AVE
SANTA ANA, CA 92799-5020
US

Emergency Phone: 800-424-9300(CHEMTREC)/202-483-7616

Info Phone: 714-953-1900/202-483-7616

Cage: 65983

BREAK-FREE INC

JACKSONVILLE, FL 32218 US

Telephone: 800-428-0588/ 904-741-5400

Cage: 65983

OILS, SYNTHETIC AND PARAFFINIC

Fraction By Weight: 55.5%

N-BUTYL ACETATE (SARA III)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 3.1%

OSHA PEL 150 PPM

ACGIH TLV: 150 PPM/200STEL;9394

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 8.7%

OSHA PEL 1000PPM

ACGIH TLV: 1000PPM/1250STEL9394

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 27.3%

OSHA PEL 350 PPM

ACGIH TLV: 350 PPM/450STEL;9394

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ISOPROPYL ALCOHOL (SARA III)

CAS: 67-63-0

RTECS: NT8050000

Fraction By Weight: 1.3%

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM/500STEL;9394

TAR ACIDS, CRESYLIC,PHENYL,PHOSPHATE

CAS: 68952-35-2

Fraction By Weight: 1.0%

CARBON DIOXIDE

CAS: 124-38-9

RTECS: FF6400000

Fraction By Weight: 2.4%

OSHA PEL 5000 PPM

ACGIH TLV: 5000PPM/30000STEL;94

BARIUM COMPOUNDS, INSOLUBLE

Fraction By Weight: 0.5% BA

TERT-BUTYL ALCOHOL (SARA III)

CAS: 75-65-0

RTECS: EO1925000

Fraction By Weight: 0.2%

OSHA PEL 100 PPM

ACGIH TLV: 100PPM; 9394

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: IN A CONFINED AREA VAPORS IN
HIGH CONCENTRATION ARE ANESTHETIC. MAY CAUSE HEADACHE, NAUSEA,
NARCOSIS, PNEUMONIA. IRRITANT TO EYES, SKIN AND UPPER RESPIRATORY
SYSTEM. CHRONIC: REPORTS HAVE ASSOC IATED REPEATED AND PROLONGED
OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN,CNS,LIVER AND KIDNEY
DAMAGE. SEE SUP. DATA.
Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS
LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN.
Effects of Overexposure:VAPORS IN HIGH CONCENTRATION ARE ANESTHETIC.
OVEREXPOSURE MAY RESULT IN FATIGUE, WEAKNESS, CONFUSION EUPHORIA,
DIZZINESS, HEADACHE, DILATED PUPILS, LACRIMATION, NERVOUSNESS,
MUSCLE FATIGUE, INSOMNIA, PARESTHESIA, DERMATITIS, PNEUMONIA,
PHOTOPHOBIA. EYE/ SKIN: IRRITATION. LIVER DAMAGE FROM HALOGENATED
SUBSTANCES.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS
OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN,
RESPIRATORY TRACT OR NERVOUS SYSTEM MAY BE AT INCREASED RISK FROM
EXPOSURE. DRYING/CRACKING OF SKIN.

First Aid:EYES: FLUSH WITH RUNNING WATER FOR 15 MINUTES WHILE HOLDING
EYELID. GET MEDICAL ATTENTION IMMEDIATELY. SKIN: WASH WITH SOAP &
WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL ADVICE.
INHALATION: REMOV E TO FRESH AIR. GIVE MOUTH-TO-MOUTH RESUSCITATION
IF NOT BREATHING. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE
VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET MEDICAL
ATTENTION IMMEDIATELY.

Flash Point Method:TCC
Flash Point:>200F,>93C
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL. WATER AND FOAM MAY CAUSE FROTHING.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE
PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. AEROSOL CANS
EXPOSED TO FIRE MAY BURST.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.

Handling and Storage Precautions:CONTENTS ARE FLAMMABLE. KEEP AWAY FROM
HEAT, SPARKS, AND OPEN FLAME. DURING USE AND UNTIL ALL VAPORS ARE
GONE: KEEP AREA VENTILATED-DO NOT SMOKE.
Other Precautions:AVOID BREATHING OF VAPORS. DO NOT STORE >120F. DO NOT
USE AROUND OPEN FLAMES. VAPORS ARE HEAVIER THAN AIR AND WILL
COLLECT IN LOW AREAS.

Respiratory Protection:WEAR A NIOSH/MSHA APPROVED RESPIRATOR IF
VENTILATION DOES NOT MAINTAIN INHALATION EXPOSURES BELOW PEL/TLV.
WEAR SELF-CONTAINED BREATHING APPARATUS IF REQUIRED FOR HIGH LEVELS
OF CONTAMINATES.
Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE
EXPOSURE IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS.
Protective Gloves:NEOPRENE,PVC OR NATURAL RUBBER GLOVES
Eye Protection:PAINT GOGGLES/SAFETY GLASSES AS REQUIRED
Other Protective Equipment:INDUSTRIAL-TYPE WORK CLOTHING, HAT AND APRON
AS REQUIRED.
Work Hygienic Practices:USE WITH ADEQUATE VENTILATION. AVOID BREATHING
VAPOR/SPRAY MIST. AVOID CONTACT WITH SKIN & EYES. WASH HANDS AFTER
USE.
Supplemental Safety and Health
AEROSOL CONTAINER WITH CONTENTS UNDER PRESSURE. DO NOT USE OR STORE
NEAR HEAT OR OPEN FLAME. DO NOT STORE ABOVE 120F. MATERIAL MAY
CONTAIN TRACES OF ORTHO-TRICRESYLPHOSPHATE (<1%) WHICH IS A
NEUROTOXI N.

HCC:V2
Boiling Pt:B.P. Text:140F,60C
Melt/Freeze Pt:M.P/F.P Text:<-75
Vapor Density:2.4 AIR=1
Spec Gravity:1.0
Solubility in Water:<1%
Appearance and Odor:LIGHT,AMBER COLOR,SLIGHT ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES
Hazardous Decomposition Products:BY FIRE: CARBON MONOXIDE, CARBON
DIOXIDE, OXIDES OF SULFUR AND NITROGEN, HYDROGEN CHLORIDE, TRACES
OF PHOSGENE.

Waste Disposal Methods:WASTE MATERIAL WILL LIKELY BE A LAND-BANNED
HAZARDOUS WASTE WHICH MUST BE DISPOSED OF ACCORDINGLY. DO NOT
INCINERATE CLOSED CONTAINER. DISPOSE OF IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATION S.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.